ChemInform Abstract: Valence‐Detrapping Modes for Electron Transfer in the Solid State of Mixed‐Valence, Oxo‐Centered, Trinuclear Iron Acetate Complexes: X‐Ray Structure and Physical Data for [Fe3O(O2CCH3)6 (4‐Et‐py)3](4‐Et‐py).

Abstract

AbstractTemp.‐dependent Mössbauer spectra of the complexes (I) and (II) and the X‐ray structure of the title compound (Ic) at 163 and 298 K (both C2/c, Z=4), which indicate more symmetric of the Fe3 triangle at the higher temp., are determined and discussed.