Abstract

Two series of heterocyclic compounds, thiazolo[3,2-a]benzimidazoles and benzimidazo[2,1-b]-1,3-thiazines, were synthesized by the tunable base-controlled regioselective cascade reaction of 2-mercaptobenzimidazole with Morita–Baylis–Hillman acetates of nitroalkenes in good yields with high regioselectivities.

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