ChemInform Abstract: Trimethylsilyl Cyanide ‐ A Reagent for Umpolung. Part 17. Diastereoselectivity in Nucleophilic Acylations of α‐Chiral Carbonyl Compounds with α,β‐Unsaturated Aldehydes After Umpolung.

S + Huenig,K Peters,H G Von Schnering,C Marschner

doi:10.1002/chin.199004104

ChemInform Abstract: Trimethylsilyl Cyanide ‐ A Reagent for Umpolung. Part 17. Diastereoselectivity in Nucleophilic Acylations of α‐Chiral Carbonyl Compounds with α,β‐Unsaturated Aldehydes After Umpolung.

S + Huenig, K Peters + Show 2 more

https://doi.org/10.1002/chin.199004104

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Journal: ChemInform

Publication Date: Jan 23, 1990

#Trimethylsilyl Cyanide #Reagent For Umpolung + Show 3 more

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Abstract

AbstractDepending on the solvent the silyl ethers (III) react with aldehydes and ketones to give 1:1 adducts, e.g. (V), (VI), (VIII) and (IX) or 2:1 adducts such as (X).

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