Abstract
An efficient method for the synthesis of novel 2-methylthio-2-alkyl/aryl-1-nitroethylenes 2 has been developed via conjugate addition-elimination of organocopper reagents to nitroketene dithioacetal 1 in the presence of TMSCl. The product nitroethylenes 2 have been further utilized for the synthesis of substituted 3-nitro-2-alkyl/arylpyrroles 5 by their reaction with aminoacetaldehyde dimethylacetal followed by acid catalyzed cyclization in ethereal HCl. The reaction of 2 with propargyl alcohol has also been investigated.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
