Abstract

Trifluoromethyl and pentafluorophenyl moieites are easily transferred to a variety of florinated inorganic and organic sulfur and carbon centers by using (trifluoromethyl)trimethylsilane and (pentafluorophenyl)trimethylsilane in the presence of catalytic a of fluoride ion. This methodology is readily applied to the simple, efficient preparation of known, previously difficult to obtain molecules, as well as a number of new perfluoroalkyl and perfluoroaryl sulfuranes, sulfoxides, ketones, esters, and alcohols

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