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Abstract
Thioamide cyclopropanes bearing phenyl substituents and thioamide- or thioester cyclopropanes bearing gem-dichloro and methyl substituents were subjected to trimethyltin radical catalyzed alkenylation to furnish the corresponding substituted (thiocarbonyl)cyclopentanes. The stereo-chemical outcome of these transformations can be rationalized by considering the effects of substituents upon cyclization of the intermediate functionalized 5-hexenyl radicals
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