Abstract
Abstract The complete vibrational spectra of crystalline sodium bromoacetate and sodium bromoacetate-d 2 have been recorded and a vibrational assignmem proposed. The intermolecular coupling of these compounds is quite strong and the data are consistent with a centrosymmetric unit cell containing at least four molecules. The product rule calculations support a structure m which the bromine atom is rotated out of the plane of the remaining heavy atoms, but the frequency of the carbon-bromine stretching mode indicates that the degree of rotation is not large.
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