Abstract

Abstract The microwave spectrum of N -methylsulfinylamine has been recorded using a pulsed molecular beam microwave Fourier transform spectrometer. The barrier to methyl internal rotation was determined to be 314.06(48) cal/mole. The quadrupole coupling constants are X aa = 0.8425(13) MHz, X bb = −2.7586(21) MHz, X cc = 1.9161(21) MHz, and X ab = 1.705(37) MHz.

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