Abstract
Abstract The infrared spectra of the cis and trans geometric isomers of methyl and ethyl propenyl ethers have been recorded in the liquid and vapour phase, in the region 4000-200 cm −1 . Solid phase spectra have also been recorded for all but trans methyl propenyl ether. Evidence is given for the existence of two rotameric forms for both the trans compounds, in each case the more stable conformer being planar s-cis; but a single non-planar conformation is suggested for the two cis isomers. The enthalpy difference between the two rotameric forms in trans ethyl propenyl ether was found to be 4.6 ± 1.0 kJ mol −1 (1100 ± 250 cal mol −1 ).
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