ChemInform Abstract: tert‐Butyl Peroxybenzoate (TBPB)‐Mediated 2‐isocyanobiaryl Insertion with 1,4‐Dioxane: Efficient Synthesis of 6‐Alkyl Phenanthridines via C(sp3)—H/C(sp2)—H Bond Functionalization.

Jia‐Jia Cao,Zheng‐Yang Gu,Xiang Wang,Shun‐Yi Wang,Shun‐Jun Ji,Tong‐Hao Zhu

doi:10.1002/chin.201444157

ChemInform Abstract: tert‐Butyl Peroxybenzoate (TBPB)‐Mediated 2‐isocyanobiaryl Insertion with 1,4‐Dioxane: Efficient Synthesis of 6‐Alkyl Phenanthridines via C(sp3)—H/C(sp2)—H Bond Functionalization.

Jia‐Jia Cao, Zheng‐Yang Gu + Show 4 more

https://doi.org/10.1002/chin.201444157

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Journal: ChemInform

Publication Date: Oct 16, 2014

Affiliation: Soochow University

#Tert-butyl Peroxybenzoate #Metal-free Conditions + Show 2 more

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Abstract

An efficient method for the construction of 6-alkyl phenanthridines by tert-butyl peroxybenzoate (TBPB)-mediated 2-isocyanobiaryl insertion with 1,4-dioxane was established. Two new C–C bonds were formed in this reaction via a sequential C(sp3)–H/C(sp2)–H bond functionalization under metal-free conditions.

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