Abstract

The syntheses and spectroscopic properties (ir, 1 H nmr, 13 C nmr, uv and ms) of pure samples of 2-chloro-4,6-bis(dimethylamino)-s-triazine 1, 4,6-dichloro-2-dimethylamino-s-triazine 2, 4,6-bis(dimethylamino)-s-triazin-2(1H)-one 3, 4-chloro-6-dimethylamino-s-triazin-2(1H)-one 4, 6-dimethylamino-s-triazine-2,4(1H,3H)- dione 5, and 2,4,6-tris(dimethylamino)-s-triazine (altretamine, HMM) are reported. Evidence for enol-keto equilibria are also presented for 3, in which the enol form exhibits as an H-bonded dimer structure similar to the dimer of organic carboxylic acids

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