Abstract
Allylic boronates are versatile intermediates in organic synthesis. Herein, we present an ‘ate-mediated allylic substitution’ (AMAS) approach to allylic boronates. Bifunctional vinylboroate/ allylic acetate esters react with Grignard reagents to form tertiary allylic boronates via an AMAS reaction. We demonstrate that the method tolerates a wide range of substrates and Grignard reagents.
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