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Abstract
AbstractDiastereoselective and diverse syntheses of polyhydroxylated indolizidines and piperidines are described, where the common chiral intermediate 2‐(hydroxymethyl) piperidine‐3‐ol is converted into 1‐deoxy‐altro‐nojirimycin derivatives (I), 1‐deoxynojirimycin (II), 1,2‐di‐epi‐swainsonine (III), swainsonine (IV), 8,8a‐di‐epi‐castanospermine (V), and isomeric pentahydroxy indolizidines (VI) and (VII).
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