Abstract
Abstract Chiral cationic and neutral Rh complexes RhX(bichep)(nbd) (XCl,ClO 4 ; nbd=norbornadiene;bichep=2,2′-bis(dicyclohexylphosphino)-6,6′-dimethyl-1,1′-biphenyl) are highly active and excellent catalysts for enantioselective hydrogenation of prochiral olefins and ketones under mild reaction conditions.
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