Abstract

AbstractThe novel title compounds M(I)4(Ni(OH)6W6O18)·nH2O (M(I): Rb, Cs, Tl; n = 5 or 6) and M(II)2(Ni(OH)6W6O18).nH2O (M(II): Ca, Sr, Ba; n = 10 or 14) are prepared in aqueous solutions by reaction of K4(Ni(OH)6W6O18)·5 H2O or (NH4)4(Ni(OH)6W6O18)·5 H2O with M(I)NO3 or M(II)(NO3)2.

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