Abstract
Abstract Novel cyclic metallatetrasulfides containing Group 14 metals have been synthesized by the thermal reactions of the corresponding metal hydrides substituted by the title new steric protection group. The structure of newly obtained metallacyclopolysulfides is of great interest in comparison with that of the previously reorted di-π-cyclopentadienylmetal pentasulfides of titanium(IV) and vanadium (IV). Attempts to prepare the metal-sulfur double bond compounds from the metallacyclopolysulfides are also described.
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