Abstract

The synthesis of substituted 1,6-dioxapyrenes from 2,6-dipropyl-1,5-naphthalenediol or 2,6-dimethyl-1,5-naphthalenediol is described.The 1,6-dioxapyrenes can be oxidized to stable cation radicals at 0.2-0.35 V vs SCE and to dications at 0.8-1.20 V.The preparation of some tetracyanoquinodimethane salts and binary cation radical salts of the 1,6-dioxapyrenes is reported

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