Abstract
Abstract In sharp contrast to the expected formation of a telluride-palladium complex, the treatment of either ( E , E )- and ( Z , Z )-distyryl tellurides ( 1 and 2 ) or ( E )- and ( Z )-styryl phenyl tellurides ( 5 and 6 ) with Li 2 PdCl 4 in acetonitrile at 25°C results in the formation of stereoisomeric 1,4-diphenylbuta-1,3-dienes, whereas the treatment of 1 and 2 with Pd(OAc) 2 produces styryl acetates solely or mainly.
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