Abstract

AbstractAnhand von IR‐Monitor‐ Untersuchungen wird gezeigt, daß die Reaktion der Komplexe (I) mit H2 ′80 unter O‐Austausch bevorzugt in den äquatorialen Carbonylliganden erfolgt und zwar stufenweise bzw. cis zum Liganden L. Der O‐Austausch am axialen CO‐Liganden erfolgt erst, wenn äquatorial tetrasubstituierte CISO‐Spezies vorliegen.

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