Abstract
Abstract The Pd II -catalyzed tandem cyclization of chiral allylic alcohols possessing an internal epoxide and a terminal alcohol provided a contiguous THF–THP and THF–THP ring units stereospecifically. The cyclizations take place via a 5- exo - tet -5- exo - trig mode, however, the cyclization of methyl substituted epoxy diols proceeded via 6- endo - tet -6- exo - trig fashion in a part to construct the oxygen-fused THP–THP ring. The different reaction rates of precursors, which are different stereochemistry at allylic alcohol have been elucidated.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
