Abstract
Stereocontrol based on the principle illustrated in 1 allows the 1,5 transfer of chiral information in some SE2″ reactions, as shown in Schemes 5 and 6, and, to some extent, the control of exocyclic double bond geometry, as shown in Schemes 15 and 16. The latter device is used in a highly stereocontrolled synthesis of the carbacyclin analogue 49.
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