Abstract
AbstractDas Tetraacetat von Secologanin (Ia) wird durch Iones‐ Oxidation, Methylierung mit Diazomethan und anschließende Zemplen‐Desacetylierung in das Methoxyderivat (Ib) umgewandelt, das nach Entfernung des Zuckerrestes mit β‐Glucosidase bei pH 6,5 mit Natriumcyanoborhydrid zur Vinylverbindung (II) reduktiv aminiert wird.
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