ChemInform Abstract: Simultaneous Presence of (Si3O10)8‐ and (Si2O7)6‐ Groups in New Synthetic Mixed Sorosilicates: BaY4(Si2O7)(Si3O10) and Isotypic Compounds, Studied by Single‐Crystal X‐Ray Diffraction, Raman Spectroscopy and DFT Calculations.

Maria Wierzbicka‐Wieczorek,Ekkehart Tillmanns,Daniel M Toebbens,Uwe Kolitsch

doi:10.1002/chin.201402013

ChemInform Abstract: Simultaneous Presence of (Si3O10)8‐ and (Si2O7)6‐ Groups in New Synthetic Mixed Sorosilicates: BaY4(Si2O7)(Si3O10) and Isotypic Compounds, Studied by Single‐Crystal X‐Ray Diffraction, Raman Spectroscopy and DFT Calculations.

Maria Wierzbicka‐Wieczorek, Ekkehart Tillmanns + Show 2 more

https://doi.org/10.1002/chin.201402013

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Journal: ChemInform	Publication Date: Dec 19, 2013
Citations: 1

Affiliation: Friedrich Schiller University Jena

#Flux Growth Method #Alkali Metal Carbonate + Show 8 more

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AbstractThe new isotypic compounds BaY4(Si2O7)(Si3O10), SrYb4(Si2O7)(Si3O10), and SrSc4(Si2O7)(Si3O10) are synthesized by a high‐temperature flux growth method from mixtures of M2O3 (M: Y, Yb, Sc), BaCO3 or Sr(OH)2, an alkali metal carbonate, and MoO3 as a flux (Pt crucibles, 1150 °C, 3 h).

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