ChemInform Abstract: Relative Electrophilic Reactivities of Tropylium Cation and Its (OC)3M π‐Complexes: Kinetic Studies of Alkoxide Transfer and Reversible Nucleophilic Addition.

K Lal,M M Mhala,N T Leckey,W E Watts,C A Bunton,J R Moffatt

doi:10.1002/chin.198841158

ChemInform Abstract: Relative Electrophilic Reactivities of Tropylium Cation and Its (OC)3M π‐Complexes: Kinetic Studies of Alkoxide Transfer and Reversible Nucleophilic Addition.

K Lal, M M Mhala + Show 4 more

https://doi.org/10.1002/chin.198841158

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Journal: ChemInform

Publication Date: Oct 11, 1988

Affiliation: University of Ulster

#Reversible Nucleophilic Addition #Complexation Of Cation + Show 8 more

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Abstract

Abstractπ‐Complexation of the tropylium cation with an Cr(CO)3 group giving (Ia) increases thermodynamic stability and reduces reactivity toward abstraction of methoxide ion from Malachite Green methyl ether (MGOMe) in MeNO2‐MeCOEt (40:60) and nucleophilic exo‐addition of methanol in methanol.

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