ChemInform Abstract: Regioselective 1,4‐Addition to α,β‐Unsaturated Ketones with Grignard Reagents Mediated by (N,N,N′,N′‐Tetramethylethylenediamine)zinc(II) Chloride.

R A Kjonaas,E J Vawter

doi:10.1002/chin.198717089

ChemInform Abstract: Regioselective 1,4‐Addition to α,β‐Unsaturated Ketones with Grignard Reagents Mediated by (N,N,N′,N′‐Tetramethylethylenediamine)zinc(II) Chloride.

R A Kjonaas, E J Vawter

https://doi.org/10.1002/chin.198717089

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Journal: ChemInform

Publication Date: Apr 28, 1987

#Grignard Reagents #Zinc Chloride + Show 2 more

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Abstract

AbstractIn the presence of the ZnCl2 complex (III), the Grignard reagents (II) react with α,β‐unsaturated ketones (I), giving predominantly the 1,4‐addition products (IV), together with small amounts of the 1,2‐addition products (V).

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