Abstract

Due to their ready availability in chiral form, and propen- sity to undergo regio- and stereoselective ring opening, aziridines have found widespread use in asymmetric synthesis. This review at- tempts to summarise the breadth of use of chiral aziridines in syn- thesis that has recently been reported. Particular emphasis is put on the effect of substituents on ring openings, rearrangements and use as chiral ligands and auxiliaries.

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