Abstract
This paper presents recent developments concerning the behaviour of the trivalent lanthanide ions in solution. Counterion complexation, coordinntion numbers and kinetic properties are discussed. Special interest is devoted to the results obtained in aqueous and N,N-dimethylformamide solutions, where the solvent exchange reactions have been characterized at variable temperature and pressure. The coordination properties, solvent exchange rates and mechanisms are discussed in terms of electrostatic and steric factors.
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