ChemInform Abstract: Preparation and Physical Properties of Trinuclear Oxo‐Centered Manganese Complexes of the General Formulation (Mn3O(O2CR)6L3)0,+ (R: Me or Ph; L: a Neutral Donor Group) and the Crystal Structures of (Mn3O(O2CMe)6(pyr)3)(pyr) and (Mn3O(O2CPh)6(pyr)2(H2O))·0,5 MeCN.

J B Vincent,J C Huffman,G Christou,K Folting,D N Hendrickson,H.-R Chang

doi:10.1002/chin.198801295

ChemInform Abstract: Preparation and Physical Properties of Trinuclear Oxo‐Centered Manganese Complexes of the General Formulation (Mn3O(O2CR)6L3)0,+ (R: Me or Ph; L: a Neutral Donor Group) and the Crystal Structures of (Mn3O(O2CMe)6(pyr)3)(pyr) and (Mn3O(O2CPh)6(pyr)2(H2O))·0,5 MeCN.

J B Vincent, J C Huffman + Show 4 more

https://doi.org/10.1002/chin.198801295

Copy DOI

Journal: ChemInform	Publication Date: Jan 5, 1988
Citations: 1

Affiliation: Indiana University Bloomington

#Oxidation Of Mn #Neutral Donor + Show 8 more

Abstract
Full-Text PDF
Similar Papers

Abstract

AbstractThe reaction of a polymeric Mn(III) acetate, readily obtained from the oxidation of Mn(II) acetate‐tetrahydrate with Bu4NMnO4, with acetic acid or benzoic acid in the presence of an excess of neutral donor ligands leads to the high‐yield formation of the trinuclear oxo‐centered Mn complexes (I).

Full Text