Abstract
A new polymer-supported BINOL (1,1‘-Bi-2-naphthol) was synthesized by coupling of aminomethyl polystyrene resin and (S)-2,2‘-dihydroxy-1,1‘-binaphthyl-3,3‘-dicarboxylic acid. This new ligand was found to be more enantioselective for the asymmetric addition of diethylzinc to aldehydes than its “free” analog [Ti(BINOL)iPrO2]. A range of 57−99% ee's as well as 78−97% yields was obtained, and the electronic properties of the enantioselectivity were also observed.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
