Abstract
We have performed an optically detected electron‐nuclear double resonance (ODENDOR) study of one of the low‐lying triplet excitations in the charge transfer complex anthracene/tetracyanobenzene. The study shows that the spectroscopic characteristics associated with this specific excitation are related to an almost complete charge transfer from anthracene to a nearest neighbor tetracyanobenzene molecule. This photoinduced charge transfer results in a reorientation of the (effectively charged) partners of the EDA complex. The possible impact of this result for the other types of low‐lying triplet excitations is discussed.
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