Year-end Sale % OFF 
Abstract
Abstract Diphosphadiselenatetrazocines, 1,5-R4P2Se2(R = Me, Et, Ph) and 1,3-R4P2N4Se2 (R = Me, Et), have been prepared in good combined yields from the cyclocondensation of R2PN2(SiMe3) with ‘SeCl3’. The compound 1,5-Ph4P2N4Se2 dissociates into Ph PN2Se radicals identified by ESR spectroscopy. Metal complexes (Ph3P2) (M = Pt, Pd) have been prepared from the reaction of 1,5-Ph4P2N4Se2 with (Ph3P)2PtC2H4 and (Ph3),Pd, respectively. The Se,Se'-dialkyl denvatives 1,5-Ph4P2N4Se2R2 undergo isomerization to produce 1,3-Ph4P2N4 2 in the solid-state (R = Me, Et) or, more rapidly, in solution (R = Me, Et, Ph).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
