Abstract

Abstract : O, O-Diethyldithiophosphatotriphenyltin(IV), C22H25O2S2Sn, crystallizes in the triclinic space group P1. The structure was determined by the heavy atom technique from 4838 reflections measured at 138 + or - 2K on an automatic difffractometer using monochromated Mo-K(alpha) radiation, to a final R-value of 0.039. The molecule contains a four-coordinate tin atom and a monodentate dithiophosphate ligand, the first such example of a dithiophosphate ligand which is neither chelating nor bridging.

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