Abstract
Abstract An efficient synthesis of fullerooxazoles was developed via PhI(OAc)2/I2-mediated [3+2] reaction of C60 with amides under photo-irradiation. The reaction was tolerant to various aryl and alkyl amides. The reaction mechanism was investigated in detail and a radical pathway was proposed for the formation of fullerooxazoles. Further transformation of compound 2l allowed the easy conjunction of fullerooxazole moiety to other molecular skeletons.
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