Abstract
AbstractThe tandem Crabbe homologation—radical rearrangement of terminal enediynes (I), (IV) and (VI) leads, in a one‐pot procedure, to the enantioselective synthesis of six‐ and seven‐membered ring α‐aminoesters (III), (V), and (VII) bearing a quaternary stereocenter based on the phenomenon of memory of chirality.
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