Abstract

Abstract The sulfonamides CF 3 SO 2 N(CH 3 )Na and CF 3 SO 2 N(H)Na have been reacted with polyfluoro cyclic, acyclic and inorganic chlorine and bromine-containing species. Nucleophilic displacement of chlorine or bromine in 1,2-dichloroperfluorocyclobutene, 1,2-dichloroperfluorocyclopentene, benzyl bromide, cyanuric chloride and oxalyl chloride has been found to occur under mild conditions to give good yields of N-substituted polyfluoroalkyl and polyfluoroaryl sulfonamides. The effects of solvent and substrate structure on the conditions necessary for reaction to occur, and the yields obtained of the desired products are discussed.

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