Abstract
Abstract The total syntheses of the herbertane sesquiterpenes (±)-herbertene ( 1 ), (±)-β-herbertenol ( 2 ) and (±)-herbertenediol ( 5 ) have been successfully accomplished involving copper-catalysed conjugate addition of Grignard reagents to unsaturated compounds and α,α-dimethylation of primary esters as key reactions.
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