Abstract
AbstractThe key steps in the synthesis of optically pure L‐daunosamine (V) are 1. the regioselective addition of phenylselenenyl chloride to the "naked sugar" (+)‐(I), followed by oxidative elimination, yielding (II), 2. the conversion of (II) to the endo‐chloroketone (III), and 3. methylation of the latter, producing mainly (IV).
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