Abstract
Abstract The molecular structure of bis ( N -chloromethyl) nitramine has been determined by gas electron diffraction. The bond lengths ( r g ), bond angles and angles of torsion (φ) with estimated total errors in parentheses are as follows: NO 1.216(3) A NN 1.422(5) A CN 1.443(4) A ClC 1.803(4) A CH 1.109(9) A ONO 128.0(14)° CNN 116.3(4)° CNC 124.8(9)° ClCN 111.6(5)° HCN 110.3(9)° φ CN 78.9(7)° φ NN 2.6(15)° The amine nitrogen has an essentially planar bond geometry. This molecule has practically C 2 symmetry. The two ClC bonds point to opposite sides of the planar C 2 NNO 2 skeleton.
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