Abstract
Abstract The microwave spectrum of cis-crotyl alcohol is reported for the normal and -OD isotopic species. The assigned transitions are consistent with a hydrogen-bonded conformation having the oxygen atom skew with respect to the CC and the hydroxylic hydrogen gauche with respect to the CC bond. The valence angles CCC and OCC are a few degrees larger than in trans-crotyl alcohol. From measurements of Stark lobes displacements the electric dipole moment has also been determined. Analysis of the A-E doublings in the ground and some torsionally excited states allowed us to infer the potential energy surfaces of the methyl and skeletal torsions and to determine kinetic and potential energy interaction between the two motions through the use of a two-dimensional flexible model.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
