Abstract

AbstractUntersuchungen zeigen, daß die aus Co(II)‐ oder Ni(II)‐acetat und 2,2′‐Bipyridyl in DMF gebildeten 1:1‐Komplexe die Michael‐Additionsreaktionen von Chalkon und seinen Derivaten (Ia,b) sowie Methylacrylat (Ic) mit Nitromethan (II) unter neutralen Bedingungen bei Raumtemp. am wirkungsvollsten von allen untersuchten Komplexen aus Co(II)‐, Cu(II)‐ und Ni(II)‐ Salzen und NN‐Liganden katalysieren.

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