Abstract

Homolytic dediazoniation of tribromo- and trichloro-benzenediazonium tetrafluoroborates in highly ionizing, low-nucleophilicity solvents (trifluoroethanol and trifluoromethanesulfonic acid (TfOH) exhibits a strong magnetic-field dependency of dediazoniation products; a more facile singlet-to-triplet intersystem crossing results in increased radical-escape products a higher magnetic fields

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