Abstract
Abstract A thermal and kinetic study of the anation-dehydration reaction of amine complexes of Co(III), Cr(III), Rh(III) and Ir(III) containing entering anions of type halo- and ciano- complexes has been carried out with isothermal and dynamic TG. The thermodinamic and kinetic parameters have been calculated using the different physical models proposed. Several of the compounds studied show disagreement with House theory, a fact which leads us to propose a greater contribution of the anion-cation volume ratio (“free space theory”), compared with the Crystal Field Activation Energy (C.F.A.E.).
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