Abstract

AbstractThe activation of arene C‐H bonds by (C5Me5)Rh(PMe3) is definitely found to proceed through an intermediate complex, described by the formulation [(C5H5)Rh(PMe3)‐(n2‐ C6H6)] on the basis of the difference in isotope effects observed during the activation of 1,3,5‐C6H3D3 vs. a 1 :1 mixture of C6H6 / C6D6.

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