ChemInform Abstract: Iridium‐Catalyzed Allylic Alkylation of Monosubstituted Allylic Acetates with Azlactone, and Separation of Diastereoisomers by Sequential Aza‐Cope Rearrangement.

Abstract

AbstractThe title reaction of oxazolone (II) with allylic acetates provides a branch‐type product as single diastereomer, whereas the other diastereomer undergoes the rearrangement to a linear alkylation product.