Abstract
Results are reported on the 193 and 248 nm photolysis of iodoethane, specifically with respect to H‐atom production. Experiments using selectively deuterated iodoethanes, ICD2CH3 and ICH2CD3, reveal that at 193 nm the carbon–hydrogen bond cleavage is not carbon‐atom specific. However, following photolysis at 248 nm, it is clear that C–H (or C–D) bond dissociation occurs preferentially at the β carbon atom.
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