Abstract

AbstractThe SN2 reaction of enantiopure sulfonate‐protected alcohols, e.g. (I) and (IV), with carboxylic acids (II) and (V) in the presence of tertiary amines (Et3N or DBU) proceeds with inversion of the stereocenter to give acyl‐protected alcohols, e.g. (III) and (VI), in good yields and high to excellent stereoselectivity.

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