Abstract
1-(1-Hydroxy-2-trimethylsilylmethylprop-2-enyl)-2-(4-methoxybut-3-enyl)-4-methoxybenzene, prepared by a short synthesis, underwent (3+2) cycloaddition to form predominantly the cis-fused tricycle 3,7-dimethoxy-1-methylene-2,3,3a,4,5,9b-hexhydro-1H-benz[e]indene upon treatment with TiCl 4 or triflic anhydride
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