Abstract
Organocatalytic asymmetric synthesis of tetrahydroquinolines has been achieved via oxidation and 1,5-hydride transfer/ring-closure cascade. The feature of this research is one-pot transformation of 3-arylprop-2-en-1-ol derivatives into tetrahydroquinolines using o-iodoxybenzoic acid-mediated oxidation and internal redox reactions. The synthetically useful ring-fused tetrahydroquinoline derivatives were obtained in moderate yields and high enantioselectivity.
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