Abstract
AbstractThe hydroboration of representative heterocycles bearing an endocyclic double bond such as (I), (IV), (V), (VII), (IX), (XI), and (XIII) with optically active diisopinocampheylborane of high enantiomeric purity (prepared from borane‐methyl sulfide and (+)‐ or ( ‐ )‐pinene, ee 92%) is investigated systematically to establish the asymm. induction.
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