Abstract
Abstract This is a review of the palladium(II)-catalyzed cyclization of unsaturated alcohols, amines, and carboxylic acids, and comprises the intramolecular oxycarbonylation of 4-penten-1,3-diols (giving cis -3-hydroxytetrahydrofuran-2-acetic acid lactones), carboxycarbonylation of 3-hydroxy-4-pentenoic acids (giving cis -3-hydroxyy-γ-butyrolactone-4-acetic acid lactones), aminocarbonylation of 3-hydroxy-4-pentenylamines (giving cis -3-hydroxypyrrolidine-2-acetic acid lactones), intramolecular di-carbonylation of homoallyl alcohols (giving γ-butyrolactone-2-acetic acid esters), 1,1-aryletherification of unsaturated alcohols (giving 2-aryl substituted 5-, 6-, 7-, and 8-membered oxygen heterocycles), and 1,1-arylamination of unsaturated amines (giving 2-aryl substituted 5- and 6-membered nitrogen heterocycles).
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